首页> 外国专利> Hydrogen peroxide production method, hydrogen peroxide production kit, organic polymer photocatalyst used for them, and their production method

Hydrogen peroxide production method, hydrogen peroxide production kit, organic polymer photocatalyst used for them, and their production method

机译:过氧化氢的生产方法,过氧化氢的生产套件,用于它们的有机聚合物光催化剂及其生产方法

摘要

The present invention provides a hydrogen peroxide production method and a hydrogen peroxide production kit that are capable of producing hydrogen peroxide more efficiently and at lower costs than conventional methods. Specifically, the present invention provides a hydrogen peroxide production method comprising: (1) a hydrogen peroxide generation step of generating hydrogen peroxide by irradiating a reaction system containing water, an organic polymer photocatalyst, and O2 with light, wherein (2) the organic polymer photocatalyst comprises an organic polymer having a structure such that a monocyclic or polycyclic aromatic compound and/or a monocyclic or polycyclic heteroaromatic compound is/are linked by a bridging group, and (3) the organic polymer has a band structure such that a conduction band (CB) has a potential lower than the potential of two-electron reduction of O2, and a valance band (VB) has a potential higher than the potential of four-electron oxidation of water.
机译:本发明提供了一种过氧化氢的生产方法和过氧化氢的生产套件,它们能够比常规方法更有效地生产并且以更低的成本生产过氧化氢。具体地,本发明提供了一种过氧化氢的制造方法,其包括:(1)通过用光照射包含水,有机聚合物光催化剂和O 2的反应体系来产生过氧化氢的过氧化氢产生步骤,其中(2)所述有机聚合物光催化剂包含具有通过桥连基团连接单环或多环芳族化合物和/或单环或多环杂芳族化合物的结构的有机聚合物,并且(3)有机聚合物具有能导带的能带结构。 (CB)的电位低于O2的两电子还原电位,价带(VB)的电位高于水的四电子氧化电位。

著录项

  • 公开/公告号JP6765132B2

    专利类型

  • 公开/公告日2020-10-07

    原文格式PDF

  • 申请/专利权人 国立大学法人大阪大学;

    申请/专利号JP20180546348

  • 发明设计人 白石 康浩;平井 隆之;

    申请日2017-10-17

  • 分类号C01B15/027;B01J31/06;B01J35/02;C08G8/22;C08L61/12;C08L65;

  • 国家 JP

  • 入库时间 2022-08-21 11:33:08

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