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Manufacturing method of petroleum needle coke for graphite electrode

机译:石墨电极用石油针状焦的制造方法

摘要

Provided are a petroleum needle coke having a sufficiently low coefficient of thermal expansion (CTE) and achieving suppression of puffing and a method of producing the petroleum needle coke. Specifically provided is a petroleum needle coke for a graphite electrode. A powder of the petroleum needle coke having a grain size of 75 µm or less is heated at 2,800°C in an argon gas atmosphere to yield a graphite powder having a loop structure that is formed by folding a stack including a plurality of stacked graphite crystal sheets, the graphite crystal sheet includes carbon atoms arranged in a plane, the graphite powder has an edge surface of the closed loop structure of the stack, and a loop formed by two adjacent layers on an innermost periphery of the stack has a stack angle of 5° or less. The stack angle is an angle formed by a tangent line at a point A and a tangent line at a point B, where each of the point A and the point B is 10 nm apart from a vertex of the loop and on the corresponding layer of the two adjacent layers along the basal plane, and the vertex of the loop is an outermost point on the edge surface of the loop on the innermost periphery.
机译:本发明提供一种具有足够低的热膨胀系数(CTE)并能抑制膨化的石油针状焦及其生产方法。具体提供了用于石墨电极的石油针状焦。将具有75μm或更小的粒度的石油针状焦的粉末在氩气气氛中在2,800℃下加热,以产生具有环状结构的石墨粉末,该环状粉末通过折叠包括多个堆叠的石墨晶体的堆叠而形成。片,石墨晶体片包括排列在平面中的碳原子,石墨粉末具有堆叠的闭环结构的边缘表面,并且由堆叠的最内周上的两个相邻层形成的环具有堆叠角为5°以下。堆叠角是由点A处的切线和点B处的切线所形成的角度,其中点A和点B中的每一个都与环的顶点相距10 nm,并且位于回路的相应层上沿基面的两个相邻层,环的顶点是环的边缘表面上最内周的最外点。

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