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Positive electrode active material for non-aqueous electrolyte secondary batteries and its manufacturing method, positive electrode mixture paste for non-aqueous electrolyte secondary batteries and non-aqueous electrolyte secondary batteries
Positive electrode active material for non-aqueous electrolyte secondary batteries and its manufacturing method, positive electrode mixture paste for non-aqueous electrolyte secondary batteries and non-aqueous electrolyte secondary batteries
It is an object of the present invention to provide a positive electrode active material for a non-aqueous electrolyte secondary battery capable of suppressing gelation of a positive electrode mixture paste in manufacturing a non-aqueous electrolyte secondary battery and improving stability. Has a layered crystal structure of a hexagonal system, the general formula (1): A Li 1 + s Ni x Co y Mn z M w B t O 2 + positive electrode active material for non-aqueous electrolyte secondary batteries represented by alpha, multiple The positive electrode active material containing a lithium metal composite oxide containing secondary particles in which primary particles are aggregated and a lithium boron compound present on at least a part of the surface of the primary particles, and is measured by a neutralization titration method. A positive electrode active material for a non-aqueous electrolyte secondary battery in which the amount of lithium hydroxide eluted when dispersed in water is 0.01% by mass or more and 0.5% by mass or less with respect to the entire positive electrode active material.
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机译:本发明的目的是提供一种用于非水电解质二次电池的正极活性材料,其能够在制造非水电解质二次电池时抑制正极合剂糊的胶凝并提高稳定性。具有六方晶系的层状晶体结构,通式(1): Sub> A Li 1 + s Ni x Co y Sub> Mn z M w B t O 2 +正用α, Sub>表示的非水电解质二次电池用电极活性物质。正极活性物质含有锂金属复合氧化物,该锂金属复合氧化物含有聚集有一次粒子的二次粒子和在其上存在的锂硼化合物。初级颗粒表面的至少一部分,并通过中和滴定法进行测定。非水电解质二次电池用正极活性物质,其中,分散于水中时的氢氧化锂的溶出量相对于正极活性物质整体为0.01质量%以上0.5质量%以下。
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