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Carbon electrode material for redox flow battery and method for producing the same

机译:用于氧化还原液流电池的碳电极材料及其制造方法

摘要

In particular, even when using a Mn-Ti-based electrolytic solution, a carbon electrode material for a redox flow battery which is excellent in oxidation resistance while stabilizing Mn ions and suppressing an increase in cell resistance during initial charge and discharge. I will provide a. The electrode material of the present invention comprises a carbonaceous fiber (A) and a carbonaceous material (B) binding the carbonaceous fiber (A), and satisfies the following requirements. (1) When the crystallite size in the c-axis direction in the carbonaceous material (B) determined by X-ray diffraction is Lc(B), Lc(B) is 10 nm or more, and (2) the carbonaceous fiber ( When the crystallite size in the c-axis direction determined by X-ray diffraction in A) is Lc(A), Lc(B)/Lc(A) is 1.0 or more, and (3) carbon electrode material surface The number of bonded oxygen atoms is 1.0% or more of the total number of carbon atoms on the surface of the carbon electrode material.
机译:尤其是,即使在使用Mn-Ti系电解液的情况下,也能够使Mn离子稳定化并抑制初期充放电时的单电池电阻的增加,并且耐氧化性优异。我会提供一个。本发明的电极材料包括碳纤维(A)和粘结碳纤维(A)的碳材料(B),并满足以下要求。 (1)当通过X射线衍射确定的碳质材料(B)在c轴方向的微晶尺寸为Lc(B)时,Lc(B)为10 nm或更大;(2)碳质纤维(当通过A中的X射线衍射确定的沿c轴方向的微晶尺寸为Lc(A)时,Lc(B)/ Lc(A)为1.0以上,并且(3)碳电极材料表面键合的氧原子为碳电极材料的表面上的碳原子总数的1.0%以上。

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