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Amphiphilic molecular sieve containing hydrophilic group on the outside and lipophilic group on the inside and production method threof

机译:含有亲水性基团,内部具有亲脂性基团的两亲性分子筛及其制备方法

摘要

The present invention provides an amphiphilic molecular sieve containing a hydrophilic group on the outside and a lipophilic group on the inside and a production method thereof. The production method comprises: dispersing the ZSM-5 spherical nano-molecular sieve into toluene, adding thereto an organosilane containing a hydrophilic group and reacting at 40-80° C. for 2-16 h, to obtain a molecular sieve containing a hydrophilic group; placing the molecular sieve containing a hydrophilic group in an aqueous solution of sodium hydroxide and reacting at 50-90° C. for 10-50 min, to obtain a molecular sieve containing a hydrophilic group on the outside; dispersing the molecular sieve containing a hydrophilic group on the outside into toluene, adding thereto an organosilane containing a lipophilic group and reacting at 40-80° C. for 2-12 h, to obtain the amphiphilic molecular sieve containing a hydrophilic group on the outside and a lipophilic group on the inside. The present invention also provides an amphiphilic molecular sieve obtained by the above production method, which contains a hydrophilic group on the outside and a lipophilic group on the inside.
机译:本发明提供了一种在外部含有亲水性基团,在内部含有亲脂性基团的两亲性分子筛及其制造方法。制备方法包括:将ZSM-5球形纳米分子筛分散于甲苯中,加入含有亲水基团的有机硅烷,在40-80℃下反应2-16h,得到含有亲水基团的分子筛。 ;将含有亲水基团的分子筛置于氢氧化钠水溶液中,于50-90℃反应10-50min,得到外侧含有亲水基团的分子筛。将外部具有亲水性基团的分子筛分散到甲苯中,向其中加入具有亲脂性基团的有机硅烷,并在40-80℃下反应2-12h,得到外部具有亲水性基团的两亲分子筛。里面有一个亲脂基团本发明还提供通过上述制造方法获得的两亲性分子筛,其在外部包含亲水基团并且在内部包含亲脂基团。

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