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Amphiphilic molecular sieve containing lipophilic group on the outside and hydrophilic group on the inside and production method thereof

机译:外部具有亲脂性基团,内部具有亲水性基团的两亲性分子筛及其制造方法

摘要

The present invention provides an amphiphilic molecular sieve containing a lipophilic group on the outside and a hydrophilic group on the inside and a production method thereof. The production method comprises: dispersing the nano-ZSM-5 molecular sieve into toluene, adding an organosilane containing a lipophilic group and reacting at 60-100° C. for 4-16 h, to obtain a molecular sieve containing a lipophilic group; placing the molecular sieve containing a lipophilic group in a mixed solution of sodium hydroxide solution and ethanol and reacting at 60-95° C. for 20-60 min, to obtain a molecular sieve containing a lipophilic group on the outside; dispersing the molecular sieve containing a lipophilic group on the outside into toluene, adding an organosilane containing a hydrophilic group and reacting at 60-100° C. for 4-16 h, to obtain the amphiphilic molecular sieve containing a lipophilic group on the outside and a hydrophilic group on the inside. The present invention also provides a molecular sieve obtained by the above production method, which does not destroy the characteristics of the original molecular sieve and has hydrophilic and lipophilic amphiphilic properties.
机译:本发明提供了一种在外部含有亲脂性基团,在内部含有亲水性基团的两亲性分子筛及其制造方法。生产方法包括:将纳米ZSM-5分子筛分散在甲苯中,加入含有亲脂基团的有机硅烷,在60-100℃下反应4-16h,得到含有亲脂基团的分子筛。将含有亲脂性基团的分子筛置于氢氧化钠溶液与乙醇的混合溶液中,在60-95℃下反应20-60min,得到外侧的具有亲脂性基团的分子筛。将外部具有亲脂性基团的分子筛分散到甲苯中,加入具有亲水性基团的有机硅烷,在60-100℃下反应4-16h,得到外部具有亲脂性基团的两亲分子筛;内部有一个亲水基团本发明还提供了通过上述生产方法获得的分子筛,其不破坏原始分子筛的特性并且具有亲水性和亲脂性两亲性。

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