In accordance with an embodiment, a carbon dioxide capturing apparatus includes a first absorbing unit, a regeneration unit, a water washing capturing unit, and a pre-amine capturing unit. The first absorbing unit brings a gas containing carbon dioxide into contact with an absorbing liquid containing an amine compound, and discharges the absorbing liquid which has absorbed carbon dioxide as a rich liquid. The regeneration unit releases a carbon dioxide gas from the rich liquid sent from the first absorbing unit. The water washing capturing unit captures the amine compound entrained in a decarbonated treatment gas sent from the first absorbing unit. The pre-amine capturing unit receives part of the rich liquid from the first absorbing unit, and traps the amine compound entrained in the decarbonated treatment gas by bringing the decarbonated treatment gas from the first absorbing unit into countercurrent contact with the part of the rich liquid.
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