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Negative electrode including SiOx particles having carbon coating, carbonaceous active material particles, and compound having carboxyl or hydroxyl group and nonaqueous electrolyte secondary batteries
Negative electrode including SiOx particles having carbon coating, carbonaceous active material particles, and compound having carboxyl or hydroxyl group and nonaqueous electrolyte secondary batteries
A negative electrode for nonaqueous electrolyte secondary batteries is provided which includes SiOx and allows the cycle characteristics of batteries to be enhanced. A negative electrode according to an example embodiment includes a negative electrode current collector and a negative electrode mixture layer disposed on the current collector. The negative electrode mixture layer includes SiOx (0.5≤x≤1.5) particles having a carbon coating on a particle surface, carbonaceous active material particles, and a compound having at least one of a carboxyl group and a hydroxyl group and having an average number of etherifying agent moieties present per unit molecule of not more than 0.8. The carbon coating includes a first coating disposed on the surface of the SiOx and a second coating disposed on the first coating and including carbon having higher crystallinity than the carbon forming the first coating.
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机译:提供了一种用于非水电解质二次电池的负极,其包括SiO x Sub>,并且可以提高电池的循环特性。根据示例实施方式的负极包括负极集流体和设置在该集流体上的负极混合物层。负极合剂层包括在粒子表面具有碳被覆的SiO x Sub>(0.5≤x≤1.5)粒子,碳质活性物质粒子,以及具有羧基和碳原子数至少之一的化合物。羟基和每单位分子中存在的平均醚化剂部分的数目不超过0.8。碳涂层包括设置在SiO x Sub>的表面上的第一涂层和设置在第一涂层上的第二涂层,所述第二涂层包括具有比形成第一涂层的碳更高的结晶度的碳。
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