METHOD FOR RECYCLING PLUTONIUM FROM SPENT RADIOACTIVE FUEL

摘要

The present invention relates to a method for recovering plutonium from spent radioactive fuel. In one embodiment, the method comprises steps of extracting tetravalent plutonium from an aqueous solution of the spent radioactive fuel using a first organic solvent comprising tributyl phosphate; reducing tetravalent plutonium to trivalent plutonium by adding to an organic phase a second organic solvent comprising dimethylhydroxylamine; and stripping plutonium into the aqueous phase for recycling by adding an aqueous dilute acid solution into an organic phase. The method can significantly improve the efficiency of recovering plutonium from spent radioactive fuel compared with HAN stripping, and at the same time, can avoid the problems resulting from U(IV) reduction and extraction.