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ANALYSIS OF SILVER ION AND COMPLEXING AGENT IN TIN-SILVER ELECTRODEPOSITION SOLUTION
ANALYSIS OF SILVER ION AND COMPLEXING AGENT IN TIN-SILVER ELECTRODEPOSITION SOLUTION
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机译:锡银电镀液中银离子和络合剂的分析
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摘要
The present disclosure relates to methods of monitoring the concentrations of silver ion and complexing agent in tin-silver (SnAg) electrodeposition solutions, and analysis and process control using such methods. Methods can include adding a precipitating agent to an electrodeposition solution including at least tin ions, silver ions, and complexing agent to cause a reaction between at least a portion of the precipitating agent and substantially all of the silver ions (to precipitate silver ions as a precipitant); adding a metallic salt to the electrodeposition solution to cause a reaction with substantially all of the remaining precipitating agent; measuring the endpoint of the silver ion back titration; further adding metallic salt to cause a further reaction with the complexing agent; and measuring the endpoint of the complexing agent titration.
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