A lead-free galvanic oxygen sensor having an aqueous electrolyte and a bismuth anode is disclosed. The electrolyte contains a polyol in addition to water and a salt. Surprisingly, a sensor with such an electrolyte has an increased resistance to passivation. The suppressed passivation of the bismuth anode leads to a sensor lifespan, in some instances, of greater than 100 days. The polyol can be added in the amount of between 20% and 30%. The polyol can comprise D-sorbitol, meso-erythritol, or glycerol. In some instances, the polyol in the electrolyte can increase the time until a sudden rise in potential for the sensor, while maintaining a constant current on the bismuth anode, of greater than 14 minutes.
展开▼
