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NOVEL MESOGEN-SILICON COMPOUND (CO)POLYMER AND THERMOPLASTIC ELASTOMER

机译:新型介晶硅化合物(CO)聚合物和热塑性弹性体

摘要

Provided is a thermoplastic elastomer comprising a mesogen-silicon compound (co)polymer which is represented by formula (1) below and has a number average molecular weight of 1,000-500,000. The thermoplastic elastomer has transparency and rubber properties (rubber elasticity) and can be (repeatedly) molded thermally and reversibly, and thus can be suitably used in potting materials or various sealing materials. In formula (1), Ar represents a mesogenic group selected from among structures represented by formula (2) below, a represents an integer of 0.5-1, b represents a number of 0-0.5 (a and b respectively represent the ratio of the number of respective repeating units to the sum of all the repeating units in the molecule, and a+b=1), R1 is a monovalent hydrocarbon group that does not contain a C1-8 aliphatic unsaturated bond, and R2 is a hydrogen atom, —Si(CH3)3, —Si(CH3)2(OH), —Si(CH3)2(CH═CH2) or —Si(CH3)2(CH2—CH═CH2).; embedded image
机译:提供了一种热塑性弹性体,其包含由下式(1)表示的液晶元-硅化合物(共)聚合物,其数均分子量为1,000-500,000。热塑性弹性体具有透明性和橡胶性质(橡胶弹性),并且可以(反复地)热可逆地成型,因此可以适合用于灌封材料或各种密封材料中。在式(1)中,Ar表示选自下式(2)表示的结构中的介晶基团,a表示0.5-1的整数,b表示0-0.5的数(a和b分别表示分子中所有重复单元的总数的总和,并且a + b = 1),R 1 是不包含C1-8脂肪族不饱和键的一价烃基,R 2 是氢原子,-Si(CH 3 3 ,-Si(CH 3 2 (OH),-Si(CH 3 2 (CH═CH 2 )或-Si (CH 3 2 (CH 2 -CH═CH 2 )。 “嵌入的图像”

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