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activator for accelerated adhesion development

机译:促进黏附发展的活化剂

摘要

the present invention relates to an activator composition comprising a) between 0.5% and 50% by weight of a catalyst k for crosslinking two-component adhesives which is liquid at 23 ° c, b) between 40% and 99% , 5% by weight of an organic solvent 1, c) between 0% and 10% by weight of at least one silane comprising at least one hydrolyzable silane group and preferably at least one functional group selected from the mercapto, epoxy, amino groups , methacryloyl, vinyl and alkyl, wherein catalyst k comprises a metal 1,3-ketoamidate complex and solvent l is selected from the group of acetone, methyl ethyl ketone, methyl n-propyl ketone, diisobutyl ketone, methyl isobutyl ketone, methyl n -amyl ketone, methyl isoamyl ketone, acetyl acetone, mesityl oxide, cyclohexanone, methyl cyclohexanone, ethyl acetate, propyl acetate, isopropyl acetate, butyl acetate, n-butyl propionate, diethyl malonate 1 -methoxy-2-propyl, 3-methoxy-n-butyl acetate, 3-ethoxypro ethyl pioneer, diisopropyl ether, diethyl ether, dibutyl ether, diethylene glycol diethyl ether, ethylene glycol diethyl ether, ethylene glycol monopropyl ether, ethylene glycol mono-2-ethylhexyl ether, ethylbenzene, toluene, xylene, heptane , octane, naphtha, turpentine, petroleum ether, benzine, methylene chloride, methanol, ethanol, isopropanol and mixtures of these solvents. the activator composition according to the invention is stable in storage for at least one month, preferably at least 2 months, in particular, at least 4 months or more without showing precipitation from the catalyst or silane. in addition, the activator composition is active regardless of the amount applied and can be applied in layers with a thickness so that the adhesive can be applied after no more than 30 seconds. the activator composition can furthermore accelerate a 2-component polyurethane adhesive in relation to the development of adhesion on the substrate, so that, after no more than an hour after application of the 2017-0055wo 27/27 adhesive, and the curing at room temperature, at least 10% of the shear bond strength achievable after 24 h of storage at room temperature has already been achieved, where the fracture pattern is as cohesive after 1 h as after 24 h.
机译:本发明涉及一种活化剂组合物,该活化剂组合物包含:a)0.5重量%至50重量%的用于使两组分粘合剂交联的催化剂k,其在23℃为液体,b)40重量%至99重量%,5重量%。 1重量%的有机溶剂,c)0-10重量%的至少一种硅烷,其包含至少一个可水解的硅烷基团,优选至少一种选自巯基,环氧基,氨基,甲基丙烯酰基,乙烯基和烷基的官能团,其中催化剂k包含金属1,3-酮氨基甲酸酯络合物,溶剂l选自丙酮,甲基乙基酮,甲基正丙基酮,二异丁基酮,甲基异丁基酮,甲基正戊基酮,甲基异戊基酮,乙酰丙酮,异亚丙基丙酮,环己酮,甲基环己酮,乙酸乙酯,乙酸丙酯,乙酸异丙酯,乙酸丁酯,丙酸正丁酯,丙二酸二乙酯1-甲氧基-2-丙基,3-甲氧基正丁基乙酸酯,3-乙氧基乙乙基先锋,二异丙醚,二乙基醚,二丁醚,二乙二醇二乙醚,乙二醇二乙醚,乙二醇单丙醚,乙二醇单-2-乙基己基醚,乙苯,甲苯,二甲苯,庚烷,辛烷,石脑油,松节油,石油醚,汽油,汽油,甲醇,乙醇,异丙醇和这些溶剂的混合物。本发明的活化剂组合物在储存至少一个月,优选至少两个月,特别是至少4个月或更长的时间内稳定,而没有从催化剂或硅烷中沉淀出来。另外,活化剂组合物是有活性的,而与所施加的量无关,并且可以以具有一定厚度的层的形式施加,使得可以在不超过30秒的时间内施加粘合剂。相对于在基材上的粘合发展,活化剂组合物还可以促进2-组分聚氨酯粘合剂的固化,因此,在施用2017-0055wo 27/27粘合剂后不超过一个小时以及在室温下固化,在室温下保存24小时后,已经达到了至少10%的剪切粘结强度,此时的断裂模式与24小时后一样具有内聚力。

著录项

  • 公开/公告号BR112020003917A2

    专利类型

  • 公开/公告日2020-09-08

    原文格式PDF

  • 申请/专利权人 SIKA TECHNOLOGY AG;

    申请/专利号BR20201103917

  • 发明设计人 CLAUDIA JUNG;MARTIN DEMMIG;RITA CANNAS;

    申请日2018-09-18

  • 分类号B32B7/12;C07F15/02;C08G18/22;C09J175/04;

  • 国家 BR

  • 入库时间 2022-08-21 11:18:19

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