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New diaryliodonium salts, methods of their preparation and use, new intermediate compounds for preparing new diaryliodonium salts and use of new intermediate compounds

机译:新的二芳基碘鎓盐,其制备和使用方法,用于制备新的二芳基碘鎓盐的新中间体化合物和新的中间体化合物的用途

摘要

The purpose of the notification is to provide new general formula diaryloidone salts (1),where E stands for anion selected from a group comprising PF6-,SbF6,BF4,CF3SO3,TsO, B (C6H5) 4, B (C6F5) 4; R1 is a substituent selected from the following: -H, -CN, -Br, -F, -Cl, COOH or the -COOCnH2n + 1 substituent, wherein n is an integer from 1 to 12, such as -COOMe, -COOEt; R2 is a substituent selected from the following: -H, -CN, -Br, -F, -Cl, -COOH or the -COOCnH2n + 1 substituent, wherein n is an integer from 1 to 12, such as -COOMe, -COOEt; R3 is a substituent selected from the following: -H, -CN, -CH3, -C2H5, -C6H5, -OCnH2n + 1, in which n is an integer from 1 to 12, such as -OCH3 or -CnH2n + 1, wherein n is an integer from 1 to 12, such as -CH3, -C2H5;R4 means the parent selected from among the following: -H, the parent -OCnH2n+1, in which n means the total number from 1 to 12, such as -OCH3; R5 means the parent selected from among the following: -H, the parent -OCnH2n+1, in which n means the total number from 1 to 12, such as -OCH3; R6 means the parent selected from among the following: -H, the parent -OCnH2n+1, where n means the total number from 1 to 12, such as -OCH3; the parent from R7 to R11 independently means: -H, -CN, -CH=C(CN)2, the group -OCnH2n+1, where n means the total number from 1 to 12, such as -OCH3, or the group -CnH2n+1,in which n is an integer from 1 to 12, linear and branched such as -CH3, -C (CH3) 3, -CH2-CH (CH3) 2. The subject of the application are also processes for the production of new diaryliodonium salts and their use as well as new intermediates used in the preparation of new diaryliodonium salts and their use.
机译:该通知的目的是提供新的通式二芳基酮盐(1),其中E代表选自PF6-,SbF6,BF4,CF3SO3,TsO,B(C6H5)4,B(C6F5)4的阴离子; R 1是选自以下的取代基:-H,-CN,-Br,-F,-Cl,COOH或-COOCnH 2n +1个取代基,其中n是1至12的整数,例如-COOMe,-COOEt ; R 2是选自以下的取代基:-H,-CN,-Br,-F,-Cl,-COOH或-COOCnH 2n +1个取代基,其中n是1至12的整数,例如-COOMe,- COOEt; R 3是选自以下的取代基:-H,-CN,-CH 3,-C 2 H 5,-C 6 H 5,-OC n H 2n +1,其中n是1至12的整数,例如-OCH 3或-C n H 2n +1。其中n是1至12的整数,例如-CH 3,-C 2 H 5; R 4表示选自以下的母体:-H,母体-OC n H 2n + 1,其中n表示1至12的总数。如-OCH3; R5是选自以下的母体:-H,母体-OCnH2n + 1,其中,n是1〜12的总数,例如-OCH3。 R6表示从以下中选择的母体:-H,母体-OCnH2n + 1,其中n表示1至12的总数,例如-OCH3; R7至R11的母体独立地表示:-H,-CN,-CH = C(CN)2,基团-OCnH2n + 1,其中n表示1到12的总数,例如-OCH3或基团-CnH2n + 1,其中n是1到12的整数,是直链和支链的,例如-CH3,-C(CH3)3,-CH2-CH(CH3)2。本申请的主题也是新的二芳基碘鎓盐的生产及其用途,以及用于制备新的二芳基碘鎓盐的新型中间体及其用途。

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