首页> 外国专利> PAINT COMPOSITION WHICH HAS EXCELLENT STAINING RESISTANCE AND PAINT FILMS OBTAINED BY COATING SAME

PAINT COMPOSITION WHICH HAS EXCELLENT STAINING RESISTANCE AND PAINT FILMS OBTAINED BY COATING SAME

机译:涂料具有相同的优异的耐沾污性和涂膜性能

摘要

[ Problem] To provide a paint composition with which it is possible to obtain paint films which not only provide staining resistance in a short period of time after coating but with which excellent staining resistance is retained over a long period of time, and with which the paint film performance required of coated steel sheets, such as water resistance, bending workability and the like, is satisfactory. [Means of Resolution] The present invention concerns a paint composition which includes a hydroxyl group-containing resin (A), a crosslinking agent (B) which reacts with hydroxyl groups, a radical copolymer (C) and an organosilica sol (D) in which the aforementioned radical copolymer (C) : (a) has a monomer composition, with respect to the total mass of radically polymerizable monomer, of from 70.0 to 99.8 mass % unsaturated carboxylic acid amide, from 0.2 to 10 mass % radically polymerizable organosiloxane and from 0 to 29.8 mass % other radically polymerizable monomer, (b) is of weight average molecular weight from 1,500 to 15,000, and (c) has a hydroxyl group value of from 10 to 50 mgKOH/ g, the aforementioned organosilica sol (D) is of average particle diameter from 1 to 30 nm, the solid fraction mass ratio represented by {the aforementioned (C) component + the aforementioned (D) component } / { the aforementioned (A) component + the aforementioned (B) component} is from 3 to 30% and the solid fraction mass ratio represented by {the aforementioned (C) component / the aforementioned (D) component} is from 0.2 to 5Ø
机译:发明内容[目的]提供一种涂料组合物,其不仅能够得到在涂布后短时间内具有耐污染性的涂料膜,而且能够长期保持优异的耐污染性。涂层钢板所需的漆膜性能,例如耐水性,弯曲加工性等令人满意。 [解决方案]本发明涉及一种涂料组合物,其包含含羟基的树脂(A),与羟基反应的交联剂(B),自由基共聚物(C)和有机硅溶胶(D)。上述自由基共聚物(C):(a)相对于自由基聚合性单体的总质量的单体组成为70.0〜99.8质量%的不饱和羧酸酰胺,0.2〜10质量%的自由基聚合性有机硅氧烷,上述有机硅溶胶(D)为0〜29.8质量%的其他自由基聚合性单体,(b)重均分子量为1,500〜15,000,(c)羟基值为10〜50mgKOH / g。当α的平均粒径为1至30nm时,由{前述(C)成分+前述(D)成分} / {前述(A)成分+前述(B)成分}表示的固体成分质量比为从3到30%a并且{上述(C)成分/上述(D)成分}表示的固体成分质量比为0.2〜5Ø

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