首页> 外国专利> CERAMIC NANOFILTRATION MEMBRANE WITH POLYMERS GRAFTED INTO THE PORES AND METHOD OF PRODUCING SAME

CERAMIC NANOFILTRATION MEMBRANE WITH POLYMERS GRAFTED INTO THE PORES AND METHOD OF PRODUCING SAME

机译:接枝到孔中的聚合物的陶瓷纳米过滤膜及其制备方法

摘要

The present invention relates to a method of manufacturing a nanofiltration membrane, comprising the steps of providing a support structure (20) comprising a first mesoporous layer (21) made of TiO2 and/or ZrO2 and a second porous layer (22) adjacent to the mesoporous layer made of aluminium oxide; grafting an anchoring group selected from the group consisting of a phosphonic acid group, a Grignard reagent, a salicylic acid group, a carbohydrate or a phtalic acid group within pores of the first mesoporous layer (21), wherein the second layer (22) is inert to the grafting step; covalently bonding an initiator for a surface initiated atom transfer radical polymerization reaction to the anchoring group; impregnating the support structure with a monomer and a solvent; and performing a polymerization reaction, comprising passing a catalyst through the mesoporous layer, the monomer being configured to start the polymerization reaction by grafting from the initiator in the presence of the catalyst. A nanofiltration membrane is provided as well.
机译:本发明涉及一种制造纳滤膜的方法,该方法包括以下步骤:提供支撑结构(20),该支撑结构包括由TiO 2 和/或ZrO 制成的第一中孔层(21)。 2 和与氧化铝制成的中孔层相邻的第二多孔层(22);在第一介孔层(21)的孔内接枝选自膦酸基,格氏试剂,水杨酸基,碳水化合物或邻苯二甲酸基团的锚定基,其中第二层(22)为对接枝步骤呈惰性;用于表面引发的原子转移自由基聚合反应的引发剂与锚定基团共价键合;用单体和溶剂浸渍载体结构;进行聚合反应,包括使催化剂通过中孔层,所述单体被配置为通过在催化剂的存在下从引发剂接枝而开始聚合反应。还提供了纳滤膜。

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