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TERNARY POSITIVE ELECTRODE MATERIAL AND PREPARATION METHOD THEREFOR, AND LITHIUM-ION BATTERY
TERNARY POSITIVE ELECTRODE MATERIAL AND PREPARATION METHOD THEREFOR, AND LITHIUM-ION BATTERY
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机译:三元正极材料及其制备方法和锂离子电池
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摘要
Provided are a ternary positive electrode material and a preparation method therefor, and a lithium-ion battery. The ternary positive electrode material comprises a micrometer-scale LiNi1-x-y-zCoxMnyMzO2 single crystal particle structure, in the formula, 0.6≤1-x-y-z1.0, 0x<0.2, 0y<0.3, and 0z0.1; the single crystal particle structure comprises a central region and a surface layer region; the molar ratio of elements in the central region satisfies Ni:Co:Mn:M=a1:x1:y1:z1, and the molar ratio of elements in the surface layer region satisfies Ni:Co:Mn:M=a2:x2:y2:z2, wherein 0.85≤a11.0, 0x1≤0.1, 0y1≤0.15, 0≤z1≤0.05, 0.3≤a2≤0.7, 0.2≤x2, y2≤0.4, and 0≤z2≤0.05, z1 and z2 are not both 0, a1/(a1+x1+y1+z1)a2/(a2+x2+y2+z2), and M is selected from at least one of Al, Mg, Ti, Ga, Nb, Zr, W, Mo, and Ta.
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机译:提供一种三元正极材料及其制备方法,以及锂离子电池。三元正极材料包括微米级LiNi 1-xyz Sub> Co x Sub> Mn y Sub> M z Sub> O < Sub> 2 Sub>单晶颗粒结构,式中0.6≤1-xyz<1.0,0 a2 /(a2 + x2 + y2 + z2),并且M选自Al,Mg,Ti,Ga,Nb中的至少一种,Zr,W,Mo和Ta。
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