首页> 外国专利> METAL-ORGANIC FRAMEWORK-BASED WATER ELECTROLYSIS CATALYST DERIVED FROM PRUSSIAN BLUE ANALOG COMPRISING THREE TRANSITION METALS AND COMPRISING SIZE-CONTROLLED PORES, AND METHOD OF PREPARING SAME

METAL-ORGANIC FRAMEWORK-BASED WATER ELECTROLYSIS CATALYST DERIVED FROM PRUSSIAN BLUE ANALOG COMPRISING THREE TRANSITION METALS AND COMPRISING SIZE-CONTROLLED PORES, AND METHOD OF PREPARING SAME

机译:包含三种过渡金属,大小受控的孔的普鲁士蓝藻类似物衍生的基于金属框架的水电解催化剂及其制备方法

摘要

Disclosed is a metal-organic framework-based water electrolysis catalyst prepared from a Prussian blue analog. The metal-organic framework-based water electrolysis catalyst comprises, as transition metals, Ni having an oxidation number of 2, Co having an oxidation number of 2, Co having an oxidation number of 3, Fe having an oxidation number of 2, and Fe having an oxidation number of 3, and comprises a coordination compound in which [Co(CN)6]3- complex ions are bonded to Ni2+, a coordination compound in which [Fe(CN)6]3- complex ions are bonded to Ni2+, and NiS produced by an ion-exchange reaction of the [Co(CN)6]3- complex ions and S2- ions.
机译:公开了一种由普鲁士蓝类似物制备的基于金属-有机骨架的水电解催化剂。基于金属-有机骨架的水电解催化剂包括作为过渡金属的,具有2的氧化数的Ni,具有2的氧化数的Co,具有3的氧化数的Co,具有2的氧化数的Fe和Fe。具有3的氧化数,并包含配位化合物,其中[Co(CN) 6 ] 3-配离子与Ni 2 + ,一种配位化合物,其中[Fe(CN) 6 ] 3-络合离子与Ni 2 + ,以及由[Co(CN) 6 ] 3-络合物离子和S < Sup> 2-离子

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