首页> 外国专利> QUADRIPOLYMER BASED ON HOST-GUEST INTERACTION AND PREPARATION METHOD THEREFOR

QUADRIPOLYMER BASED ON HOST-GUEST INTERACTION AND PREPARATION METHOD THEREFOR

机译:基于宿主-客体相互作用的四元共聚物及其制备方法

摘要

Disclosed are a quadripolymer based on a host-guest interaction and a preparation method therefor. The preparation process involves: (1) weighing maleic anhydride, dissolving same in dichloromethane, dropwise adding β-phenylethylamine, stirring and reacting same for 1-3 hours, and suction filtering, washing and vacuum drying same to obtain N-phenylethylmaleamic acid; (2) weighing mono-6-ethylenediamine β-cyclodextrin and maleic anhydride, dissolving same in N,N-dimethylformamide, reacting same for 3-6 h at 40℃, allowing a product to precipitate out by using chloroform, and washing and vacuum drying same to obtain maleic anhydride-modified mono-6-ethylenediamine β-cyclodextrin; and (3) adding acrylamide, acrylic acid, the maleic anhydride-modified mono-6-ethylenediamine β-cyclodextrin and N-phenylethylmaleamic acid to distilled water, adjusting the pH value of the solution to 7, introducing nitrogen to remove oxygen, adding a photoinitiator, and placing same in a light-initiation device for a reaction of 3-5 hours at a reaction temperature of 10-30℃. The quadripolymer has a better temperature and salt resistance and shear resistance, the raw materials thereof are cheap and easily available, and the reaction conditions are mild. Same has broad market application prospects.
机译:公开了一种基于主体-客体相互作用的四元共聚物及其制备方法。制备过程包括:(1)称量马来酸酐,溶于二氯甲烷,滴加β-苯乙胺,搅拌搅拌反应1-3小时,抽滤,洗涤,真空干燥,得到N-苯乙基马来酸。 (2)称量单-6-乙二胺β-环糊精和马来酸酐,将其溶解于N,N-二甲基甲酰胺中,在40℃下反应3-6h,然后用氯仿使其析出,并进行洗涤和真空。将其干燥以获得马来酸酐改性的单-6-乙二胺β-环糊精。 (3)在蒸馏水中加入丙烯酰胺,丙烯酸,马来酸酐改性的单-6-乙二胺β-环糊精和N-苯基乙基马来酰胺酸,调节溶液的pH值至7,通入氮气脱氧,光引发剂,将其置于光引发装置中,在10-30℃的反应温度下进行3-5小时的反应。该四元共聚物具有较好的温度和耐盐性和抗剪切性,其原料便宜且易于获得,并且反应条件温和。同样具有广阔的市场应用前景。

著录项

  • 公开/公告号WO2020093445A1

    专利类型

  • 公开/公告日2020-05-14

    原文格式PDF

  • 申请/专利权人 SOUTHWEST PETROLEUM UNIVERSITY;

    申请/专利号WO2018CN116450

  • 发明设计人 REN QIANG;LI YONGMING;JIANG YOUSHI;

    申请日2018-11-20

  • 分类号C08F290/02;C08F220/56;C08F220/06;C08F220/54;

  • 国家 WO

  • 入库时间 2022-08-21 11:11:17

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