首页> 外国专利> ACID-TYPE SULFONATE GROUP-CONTAINING POLYMER, LIQUID COMPOSITION, SOLID POLYMER ELECTROLYTE MEMBRANE, MEMBRANE ELECTRODE JOINT BODY, SOLID POLYMER FUEL CELL, AND ION EXCHANGE MEMBRANE FOR WATER ELECTROLYSIS

ACID-TYPE SULFONATE GROUP-CONTAINING POLYMER, LIQUID COMPOSITION, SOLID POLYMER ELECTROLYTE MEMBRANE, MEMBRANE ELECTRODE JOINT BODY, SOLID POLYMER FUEL CELL, AND ION EXCHANGE MEMBRANE FOR WATER ELECTROLYSIS

机译:含酸性磺酸盐基团的聚合物,液体组成,固体聚合物电解质膜,膜电极接头体,固体聚合物燃料电池和用于水电解的离子交换膜

摘要

Provided are: an acid-type sulfonate group-containing polymer that has excellent hydrogen gas barrier properties and hot water resistance and that generates less oligomer during production; a liquid composition and a solid polymer electrolyte membrane including the acid-type sulfonate group-containing polymer; and a membrane electrode joint body and a solid polymer fuel cell provided with the solid polymer electrolyte membrane. This acid-type sulfonate group-containing polymer has a perfluoromonomer unit, has no monomer unit having a halogen atom other than a fluorine atom, and has an acid-type sulfonate group, wherein: the hydrogen gas permeability coefficient under a condition of a temperature of 80°C and a relative humidity of 10% is less than or equal to 2.5×10-9cm3∙cm/(s∙cm2∙cmHg); the mass decrease rate when being immersed in hot water for 24 hours at 120°C is less than or equal to 15 mass%; and the capacity flow rate value of a polymer having a fluorosulfonyl group which is a precursor of a polymer having the acid-type sulfonate group is greater than or equal to 220°C.
机译:提供:具有优异的氢气阻隔性和耐热水性并且在生产过程中产生较少的低聚物的含酸型含磺酸盐基团的聚合物;和液体组合物和固体高分子电解质膜,其包含含酸型磺酸酯基的聚合物。膜电极接合体和具备该固体高分子电解质膜的固体高分子燃料电池。该含酸型磺酸酯基的聚合物具有全氟单体单元,不具有除氟原子以外的具有卤原子的单体单元,并且具有酸型磺酸酯基,其中:温度条件下的氢气渗透系数。 80°C且相对湿度10%≤2.5×10 -9 cm 3 ∙cm /(s∙cm 2 < / Sup>∙cmHg);当在120℃的热水中浸泡24小时时的质量下降率小于或等于15质量%。并且,具有酸型磺酸酯基的聚合物的前体即具有氟磺酰基的聚合物的容量流量值为220℃以上。

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