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FLAME RETARDANT MIXTURES, FLAME-RETARDANT POLYMER COMPOSITIONS, CABLES ENDOWED THEREWITH AND USE THEREOF

机译:阻燃混合物,阻燃聚合物组合物,赋予其的电缆及其用途

摘要

Flame retardant mixtures, flame-retardant polymer compositions, cables endowed therewith and use thereof What are described are flame retardant mixtures comprising a) salt of a phosphinic acid of the formula (I) in which R1and R2 are independently alkyl, cycloalkyl, aryl or aralkyl that are optionally substituted, M is an m-valent cation, and m is 1 to 4, b) salt of a phosphinic acid of the formula (II) that differs from component a) in which R3 is optionally substituted alkyl, cycloalkyl, cycloalkylalkyl, aryl or aralkyl, preferably with alkyl radicals as substituents, R4 is alkyl with an even number of carbon atoms, with the proviso that, if R1 and/or R2 are alkyl, R4 has twice, three times or four times the number of carbon atoms of R1or R2, M is an n-valent cation, and n is 1 to 4, c) organylphosphonate, d) phosphite, e) silicate, alumosilicate and/or silicon dioxide which is solid at 25°C, f) a representative selected from the group of triazine complex, polyphosphate, hypophosphite, nitrogen-containing diphosphate, organophosphate, phosphazene and/or polyphosphonate, g) optionally a representative selected from the group of metal hydroxide, metal carbonate, metal borate, zinc stannate and/or intumescent additive, and h) optionally pigment. The mixtures can be used for production of flame-retardant polymer compositions comprising thermoplastic and elastomeric polymers that are of excellent suitability for production of cable sheaths or cable insulations.
机译:阻燃剂混合物,阻燃剂聚合物组合物,赋予其的电缆及其用途描述了包括a)式(I)的次膦酸的盐的阻燃剂混合物,其中R 1 和R 2 独立地是任选取代的烷基,环烷基,芳基或芳烷基,M是m价阳离子,并且m是1-4,b)式(II)的次膦酸的盐不同于组分a),其中R 3 是任选取代的烷基,环烷基,环烷基烷基,芳基或芳烷基,优选以烷基为取代基,R 4 是具有碳原子数为偶数,条件是,如果R 1 和/或R 2 是烷基,则R 4 具有两倍,三倍或是R 1 或R 2 的碳原子数的四倍,M是n价阳离子,n为1-4,c)有机膦酸酯,d)亚磷酸盐,e)硅酸盐,铝硅酸盐和/或二氧化硅,在25°C,f)选自三嗪配合物,多磷酸盐,次磷酸盐,含氮二磷酸盐,有机磷酸盐,磷腈和/或多膦酸盐的代表,g)任选选自金属氢氧化物,金属碳酸盐,金属的代表硼酸盐,锡酸锌和/或膨胀型添加剂,以及h)可选颜料。所述混合物可用于生产包含热塑性和弹性聚合物的阻燃聚合物组合物,所述阻燃聚合物组合物非常适合于生产电缆护套或电缆绝缘体。

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