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THERMALLY ACTIVATED DELAYED FLUORESCENCE MATERIAL AND PREPARATION METHOD THEREFOR, AND ORGANIC LIGHT-EMITTING DIODE DEVICE

机译:热活化的延迟荧光材料及其制备方法和有机发光二极管装置

摘要

The present invention relates to a thermally activated delayed fluorescence (TADF) material and a preparation method therefor, and an organic light-emitting diode device. The structural general formula of the TADF material is as shown in the following formula I: (I), R representing a chemical group as an electron donor. The TADF material of the present invention has an ultrafast reverse intersystem crossing rate and high luminous efficiency, and is a blue TADF material having significant TADF characteristics and high energy level. According to the present invention, 100% internal quantum utilization efficiency of the TADF material is used, and the TADF material, as the main material of a conventional fluorescence material, is applied to an organic light-emitting diode device, so that a fluorescent device can achieve device efficiency comparable to the phosphorescent device of a phosphorescent heavy metal complex, thereby greatly improving the exciton utilization rate, and solving the problems such as poor color gamut and overlong exciton service life caused by directly using the TADF material as the material of a light-emitting layer.
机译:本发明涉及一种热活化延迟荧光(TADF)材料及其制备方法,以及有机发光二极管装置。 TADF材料的结构通式如下式I所示:(I),R表示作为电子供体的化学基团。本发明的TADF材料具有超快的逆系统间交叉速率和高发光效率,并且是具有显着的TADF特性和高能级的蓝色TADF材料。根据本发明,使用TADF材料的100%内部量子利用效率,并且TADF材料作为常规荧光材料的主要材料被应用于有机发光二极管装置,从而荧光装置可以达到与磷光重金属配合物的磷光器件相当的器件效率,从而大大提高了激子利用率,并解决了直接使用TADF材料作为材料而引起的色域差和激子使用寿命过长等问题。发光层。

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