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STRUCTURAL ADHESIVE AND BONDING APPLICATION THEREOF

机译:结构胶及其粘接应用

摘要

Structural adhesive composition suitable for high strength bonding of metals and aircraft structural materials. In one embodiment, the structural adhesive composition based on a two part system curable at 200 ° F. (93 ° C.) or less. The two-part system consists of a resin portion (A) and a catalyst portion (B) which can be stored independently at room temperature until ready for use. The resin portion (A) is composed of at least two different multifunctional epoxy resins having different functional groups selected from difunctional, trifunctional and tetrafunctional epoxy resins, inorganic filler particles as specific toughening components and rheology / tetramodity modifying components. It includes. The toughening component includes at least one of core-shell rubber particles and elastomeric polymers and polyethersulfone polymers having different particle sizes. The catalyst portion (B) comprises an aliphatic or cyclic amine compound as the curing agent and an inorganic filler as the rheology / terotropic modifying component. The weight ratio of parts (A) to (B) is in the range of 3: 2 to 10: 2. In another embodiment, the structural adhesive composition is based on a one part system comprising the components of the resin portion (A) in a two part system, mixed with a latent amine curing agent. The one part system may further comprise imidazole and / or aliphatic amines. One-part systems are curable within a temperature range of 140-300 ° F. (60-150 ° F.). The paste adhesives disclosed herein have film-like properties and are particularly useful in the field of fast assembly airplane structure bonding .
机译:适用于金属和飞机结构材料的高强度粘结的结构粘合剂组合物。在一个实施方案中,基于两部分体系的结构粘合剂组合物可在200°F(93°C)或更低的温度下固化。该两部分系统由树脂部分(A)和催化剂部分(B)组成,它们可以在室温下独立存放直至准备使用。树脂部分(A)由至少两种不同的具有不同官能团的多官能环氧树脂组成,所述官能团选自双官能,三官能和四官能环氧树脂,作为特定增韧组分的无机填料颗粒和流变/四官能改性组分。这包括。增韧组分包括核-壳橡胶颗粒和具有不同粒径的弹性体聚合物和聚醚砜聚合物中的至少一种。催化剂部分(B)包含脂族或环状胺化合物作为固化剂和无机填料作为流变/变质改性组分。部分(A)与(B)的重量比在3:2至10:2的范围内。在另一个实施方案中,结构粘合剂组合物基于包含树脂部分(A)的组分的单部分体系。在两部分系统中,与潜在的胺固化剂混合。单部分系统可以进一步包含咪唑和/或脂族胺。一件式系统可在140-300°F(60-150°F)的温度范围内固化。本文公开的糊状粘合剂具有薄膜状的特性,在快速组装飞机结构粘合领域特别有用。

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