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New alkyldiphenylmethane protective agent
New alkyldiphenylmethane protective agent
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机译:新型烷基二苯基甲烷保护剂
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摘要
Provides an alkyldiphenylmethane protecting agent that facilitates separation and purification after the reaction without solidifying or insolubilizing the compound protecting the functional group. General Formula (1) (In the formula, Y is -OR 19 (wherein R 19 represents a hydrogen atom or an active ester type protecting group), -NHR 20 (where R 20 is a hydrogen atom, a straight chain having 1 to 6 carbon atoms or Represents a branched alkyl group or aralkyl group), an isocyanate group, an azide group, or a halogen atom, Z represents a C 1 to C 4 linear or branched alkyl group or alkenyl group, or a cycloalkyl group, R 1 to At least one of R 10 represents a group represented by formula (2), and the rest represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 4 carbon atoms or an alkoxy group having 1 to 4 carbon atoms; R 11 is a straight chain having 1 to 16 carbon atoms Or a branched chain alkylene group; X represents O or CONR 21 (here, R 21 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms); A represents formula (3) and the like (here R 12 , R 13 and R 14 are the same or different, and represent a C 1 to C 6 linear or branched alkyl group or an aryl group which may have a substituent; R 15 is a single bond or a C 1 to C 3 linear or branched alkylene A group, and R 16 , R 17, and R 18 each represent a linear or branched alkylene group having 1 to 3 carbon atoms).
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