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METHOD OF PREPARING CATALYST FOR MEDIUM-TEMPERATURE CONVERSION OF CARBON OXIDE WITH STEAM

机译:一种蒸汽中温转化催化剂的制备方法

摘要

FIELD: chemistry.;SUBSTANCE: invention relates to chemical industry, specifically to a method of producing catalysts for medium-temperature conversion of carbon oxide with steam, which can be used in preparing a nitrogen-hydrogen mixture for ammonia synthesis. In the method of preparing a catalyst for medium-temperature conversion of carbon oxide with steam, involving mechanical activation of an iron-containing component with a copper compound in the presence of oxalic acid, mixing the mass, molding, drying and calcining granules, according to invention as iron-containing component there used is mixture of metal iron powder and spent iron-chromium catalyst at weight ratio Fe / catalyst = (1÷4):(4÷1) with subsequent calcination, addition of 0.5÷6.0 wt% of chromic anhydride, followed by stirring.;EFFECT: technical result consists in increase in specific surface area and high thermal stability of catalyst.;1 cl, 1 tbl, 3 ex
机译:化学领域本发明涉及化学工业,特别是涉及一种用于用蒸汽对二氧化碳进行中温转化的催化剂的制备方法,该催化剂可用于制备用于氨合成的氮-氢混合物。在制备用于用蒸汽对二氧化碳进行中温转化的催化剂的方法中,涉及在草酸存在下用铜化合物将含铁组分与铜化合物机械活化,将物料混合,模制,干燥和煅烧。对于本发明,作为含铁组分,使用金属铁粉和废铁-铬催化剂的混合物,其重量比为Fe /催化剂=(1÷4):( 4÷1),随后煅烧,添加0.5÷6.0 wt%效果:技术成果包括增加比表面积和催化剂的高热稳定性。; 1 cl,1 tbl,3 ex

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