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ELECTROLYSIS CELL FOR SEPARATION OF LOW-MELTING ALLOYS BY ELECTROLYSIS IN MOLTEN SALTS

机译:通过电解分离盐中的低熔点合金的电解槽

摘要

FIELD: physics; chemistry.;SUBSTANCE: invention relates to an electrolysis cell for separating wastes of fusible alloys into selective concentrates by electrolysis in molten salts. Electrolysis cell comprises a heated bath of heat-resistant electrically insulating material, an anode and a cathode, separated by a package of diaphragms impregnated with electrolyte, wherein a package of diaphragms consists of sections of diaphragms, each of which consists of two flat annular gaskets with an oval ledge, where a lower annular gasket in the cylindrical part is glued with a diaphragm from quartz fabric, and on the ledge has a hole, and on upper annular gasket from below on cylindrical part there is a diaphragm of graphite fabric. Upper annular gasket along periphery is glued with lower annular gasket into section, and sections of diaphragms in package along periphery along common axis are glued symmetrically with offset from each other by oval ledges. Lower sections of diaphragm package are immersed into molten initial alloy -anode on support, and under holes of lower section track there are vessels of product collectors. In the gap between the wall of the vessel and the package of diaphragms there is a quartz tube with a lower bevel for filling the initial anode alloy, and in the opposite end of the vessel there is a container for collection of the spent anode. Electrolyte for impregnation of diaphragms contains lithium chloride, sodium chloride and potassium chloride, with the following ratio (wt. %): lithium chloride - 40–42; sodium chloride - 8–9; potassium chloride is balance.;EFFECT: higher selectivity of separation of metals and specific capacity due to possibility of increasing current.;4 cl, 3 dwg
机译:领域:物理学;电解池技术领域本发明涉及一种电解池,该电解池用于通过在熔融盐中进行电解将易熔合金的废物分离成选择性的精矿。电解池包括一个由耐热电绝缘材料制成的加热浴,一个阳极和一个阴极,并由一叠充满电解质的隔膜分隔开,其中,一组隔膜由多个隔膜部分组成,每个隔膜由两个扁平的环形垫圈组成带有一个椭圆形的壁架,其中圆柱形部分的下部环形垫圈用石英纤维制成的膜片粘接,并且在壁架上有一个孔,而在圆柱形部分下部的上部环形垫圈上则是石墨织物的膜片。沿上边缘的上环形垫圈与下环形垫圈粘在一起,将包装中的隔膜沿公共轴沿周向的部分对称地粘在一起,并通过椭圆形壁架相互偏移。隔膜包装的下部浸入支撑中的熔融初始合金阳极中,下部轨道的孔下方有产品收集器的容器。在容器壁和隔膜包装之间的间隙中,有一个石英管,带有一个下斜面,用于填充初始阳极合金,在容器的另一端,有一个用于收集废阳极的容器。用于膜片浸渍的电解液包含氯化锂,氯化钠和氯化钾,其比率(重量%)如下:氯化锂-40–42;氯化钠-8–9;氯化钾是平衡的;效果:由于电流增加的可能性,金属分离的选择性更高,比容量更高; 4 cl,3 dwg

著录项

  • 公开/公告号RU2727365C2

    专利类型

  • 公开/公告日2020-07-21

    原文格式PDF

  • 申请/专利权人 DYAKOV VITALIJ EVGENEVICH;

    申请/专利号RU20190136936

  • 发明设计人 DYAKOV VITALIJ EVGENEVICH (RU);

    申请日2019-11-18

  • 分类号C25C7;

  • 国家 RU

  • 入库时间 2022-08-21 11:02:21

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