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METHOD OF PRODUCING 1,9-(1',4'-OXATHIANO)-1,9-DIHYDRO-(C60-IH5,6FULLERENE
METHOD OF PRODUCING 1,9-(1',4'-OXATHIANO)-1,9-DIHYDRO-(C60-IH5,6FULLERENE
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机译：制备1,9-（1'，4'-OXATHIANO）-1,9-二氢-（C 60 -I H ] [5,6]富勒烯的方法
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摘要
FIELD: chemistry.;SUBSTANCE: invention relates to a method of producing 1,9-(1',4'-oksatiano)-1,9-dihydro-(C60-Ih][5,6]fullerene of formula (1).; ;Inventive method comprises reacting bifunctional mercaptoalcohols (2-mercaptoethanol, 1-mercapto-2-propanol, 2-mercapto-3-butanol) and fullerene C60 in the presence of solid LiOH under ultrasound action in molar ratio C60 : mercaptoalcohols : LiOH ratio equal to 1:20–700:40–500, in air at room temperature in a medium of toluene for 1 hour and subsequent extraction of the end product using preparative high-performance liquid chromatography (HPLC).;EFFECT: method of selective production of 1,9-(1',4'-oksatiano)-1,9-dihydro-(C60-Ih][5,6]fullerene of formula (1) in high yield (91 %); obtained compound can be used as synthon for synthesis of derivatives of oxathian C60, having insecticidal, acaricidal, fungicidal and antibacterial activities, as well as in production of nanomaterials.;1 cl, 1 tbl, 1 ex
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机译：技术领域本发明涉及一种生产1,9-（1'，4'-oksatiano）-1,9-dihydro-（C 60 -I h的方法] [5,6]式（1）的富勒烯。 ;本发明的方法包括在固态LiOH存在下，在超声作用下，在固体LiOH存在下，使双官能巯基醇（2-巯基乙醇，1-巯基-2-丙醇，2-巯基-3-丁醇）与富勒烯C 60 反应C 60 的比例：巯基醇：LiOH的比例等于1：20–700：40–500，在室温下在空气中的甲苯介质中放置1小时，然后使用制备高浓度的水萃取最终产物高效液相色谱法;效果：选择性生产1,9-（1'，4'-oksatiano）-1,9-dihydro-（C 60 -I h ] [5,6]式（1）的富勒烯，收率高（91％）;所得化合物可作为合成子用于合成oxathian C 60 的衍生物杀虫，杀螨，杀真菌和抗菌活性以及纳米材料的生产。; 1 cl，1 tbl，1 ex
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