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Plasticization of Bloodmeal-based Thermoplastics

机译:血粉基热塑性塑料的增塑

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摘要

Water is the most common plasticizer for proteinbased thermoplastics, lowering the softening point to a allow processing without excessive degradation. The biggest drawback of using water a plasticizer is that water easily evaporates from the material during use or storage. This leads to embrittlement and loss of functionality over time. In this study a series of high molecular mass plasticizers were evaluated for their efficiency in plasticizing bloodmeal-based thermoplastics. It was found that propylene glycol, di and tri-ethylene glycol were most efficient in increasing the material’s ductility, as measured by elongation at break. Using 10 parts plasticizer per hundred bloodmeal (pphBM) in combination with 10 pphBM urea gave optimal results in terms of Young’s modulus, tensile strength and processability. The mechanical properties of plasticized samples showed a stronger dependency on moisture content, compared to unplasticized samples and reached higher equilibrium moisture content in a shorter time. Using 10 pphBM TEG as plasticizer in resulted in a plastic material with a Young’s modulus of 869 MPa, tensile strength of 14.7 MPa and an elongation at break of 46%.
机译:水是蛋白质基热塑性塑料最常见的增塑剂,可将软化点降低至允许加工而不会过度降解的程度。使用水作为增塑剂的最大缺点是,在使用或储存期间,水很容易从材料中蒸发掉。随着时间的流逝,这导致脆化和功能丧失。在这项研究中,评估了一系列高分子增塑剂在增塑血粉基热塑性塑料中的效率。通过断裂伸长率测得,发现丙二醇,二乙二醇和三乙二醇最有效地提高了材料的延展性。每100份血粉(pphBM)加入10份增塑剂与10 pphBM尿素相结合,就杨氏模量,抗张强度和可加工性而言,可获得最佳结果。与未塑化样品相比,塑化样品的机械性能显示出对水分含量的更强依赖性,并在较短时间内达到了更高的平衡水分含量。使用10 pphBM TEG作为增塑剂,得到的塑料材料的杨氏模量为869 MPa,拉伸强度为14.7 MPa,断裂伸长率为46%。

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