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Mechanical durability of superhydrophobic surfaces: the role of surface modification technologies

机译:超疏水表面的机械耐久性:表面改性技术的作用

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摘要

Various surface modification technologies have been used to develop superhydrophobic surface, however their durability has been recognized as the major obstacle for the real applications. Here a quantitative investigation was conducted to evaluate the effects of different surface modification methods on the surfaces’ mechanical durability. The superhydrophobic surfaces were prepared by the combination of two surface roughing methods (etching and sandblasting) with chemical modifications with four low surface energy materials: silica sol (SS), octadecanoic acid (OA), heptadecafluoro-1,1,2,2-tetrahydrodecyltrichlorosilane (HDFS) and hexadecyltriethoxysilane (HTS). XPS was used to analyze the elements composition and AFM was used to measure the roughness of the surfaces. The durability of these surfaces was tested by a sandpaper abrasion experiment. The collective results showed that the low surface energy materials had significant effects on the surface roughness, which would then play an important role in the durability of these rough surfaces. The SS modified rough surfaces possessed higher roughness and better durability than the surfaces modified by other three low surface energy materials. SS modified rough surfaces could bear 60 cycles of abrasion with 10 g weights on 1500 CW sandpaper.
机译:各种表面改性技术已用于开发超疏水性表面,但是其耐用性已被认为是实际应用的主要障碍。在这里进行了定量研究,以评估不同表面改性方法对表面机械耐久性的影响。超疏水性表面是通过两种表面粗化方法(蚀刻和喷砂)结合化学改性和四种低表面能材料而制备的:四种低表面能材料:硅溶胶(SS),十八烷酸(OA),七氟-1,1,2,2-四氢癸基三氯硅烷(HDFS)和十六烷基三乙氧基硅烷(HTS)。 XPS用于分析元素组成,AFM用于测量表面粗糙度。这些表面的耐久性通过砂纸磨耗实验进行测试。总体结果表明,低表面能材料对表面粗糙度有显着影响,这将在这些粗糙表面的耐久性中发挥重要作用。 SS改性的粗糙表面比其他三种低表面能材料改性的表面具有更高的粗糙度和更好的耐久性。 SS改性的粗糙表面在1500 CW砂纸上可以承受60次循环磨损,重10 g。

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