Advanced sulfur control concepts in hot-gas desulfurization technology. Quarterly report, April 1--June 30, 1998

摘要

Twenty-five reduction/sulfidation tests plus one sulfidation/regeneration test were completed during the quarter. The reduction/sulfidation tests examined the behavior of six cerium oxide sorbents from different sources with reaction variables of temperature, pressure, gas composition and flow rate. Most significantly, steam was added to the sulfidation feed gas for the first time. Tests using pre-reduced sorbents and tests in which reduction and sulfidation occurred simultaneously were performed. Prebreakthrough H(sub 2)S concentrations less than 10 ppmv were obtained over a range of reaction conditions with prebreakthrough concentrations as low as 1 ppmv achieved at the most favorable conditions. The general response to reaction variables was as expected except when feed rate was varied. In some of these cases the FPD breakthrough time did not correspond to expectation. The single regeneration run was conducted at 600 C and 2 atm using 12% SO(sub 2) in N(sub 2) at a feet rate of 400 sccm. This was the first regeneration test at other than 1 atm pressure; favorable results were obtained. The only experimental objective remaining is additional high pressure regeneration testing.