Radionuclide Leaching from Residual Solids Remaining after Acid Dissolution of Composite K East Canister Sludge

摘要

Laboratory tests were performed to examine mixed nitric/hydrofluoric acid leach treatments for decontaminating dissolver residual solids (KECDVSR24H-2) produced during a 20- to 24-hr dissolution of a composite K East (KE) Basin canister sludge in 95 C 6 M nitric acid (HNO(sub 3)). The scope of this testing has been described in Section 4.5 of 'Testing Strategy to Support the Development of K Basin Sludge Treatment Process' (Flament 1998). Radionuclides sorbed or associated with the residual solids generated in the K Basin sludge treatment process can restrict disposal of this solid to the Environmental Restoration Disposal Facility (ERDF). The starting dissolver residual solid for this testing, KECDVSR24H-2, contains radionuclides at concentrations which exceed the ERDF Waste Acceptance Criteria for TRU by about a factor of 70, for (sup 239)Pu by a factor of 200, and for (sup 241)Am by a factor of 50. The solids also exceed the ERDF criterion for (sup 137)Cs by a factor of 2 and uranium by a factor of 5. Therefore, the radionuclides of greatest interest in this leaching study are first (sup 239)Pu and (sup 241)Am (both components of TRU) and then uranium and (sup 137)Cs.