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Connection Between Chemical Rate Coefficients and Two-Particle Correlation Functions in Aggregated Systems

机译:化学速率系数与聚合系统中双粒子相关函数的关系

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The forward direction rate coefficient lambda of irreversible biomolecular reaction A + B implies C is expressed in terms of the average velocities and of the spatial correlation of reactants. The anisotropic conditions supposed in microaggregates result in a formula differing from that in isotropic liquids. This difference ensures a conceptual possibility to explain the deviation of rate coefficients observed in microaggregates from those observed in conventional solutions. (ERA citation 07:044283)

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