Pilot-Scale Demonstration of ALTA for NO(sub x) Control in Pulverized Coal-Fired Boilers. Final Technical Report for September 1, 2005 to April 30, 2008

摘要

This report describes computational fluid dynamics (CFD) modeling and pilot-scale testing conducted to demonstrate the ability of the Advanced Layered Technology Approach (ALTA) to reduce NO(sub x) emissions in a pulverized coal (PC) boiler. Testing specifically focused on characterizing NO(sub x) behavior with deep burner staging combined with Rich Reagent Injection (RRI). Tests were performed in a 4 MBtu/hr pilot-scale furnace at the University of Utah. Reaction Engineering International (REI) led the project team which included the University of Utah and Combustion Components Associates (CCA). Deep burner staging and RRI, combined with selective non-catalytic reduction (SNCR), make up the Advanced Layered Technology Approach (ALTA) for NO(sub x) reduction. The application of ALTA in a PC environment requires homogenization and rapid reaction of post-burner combustion gases and has not been successfully demonstrated in the past. Operation of the existing low-NO(sub x) burner and design and operation of an application specific ALTA burner was guided by CFD modeling conducted by REI. Parametric pilot-scale testing proved the chemistry of RRI in a PC environment with a NOx reduction of 79% at long residence times and high baseline NOx rate. At representative particle residence times, typical operation of the dual-register low-NO(sub x) burner provided an environment that was unsuitable for NO(sub x) reduction by RRI, showing no NOx reduction. With RRI, the ALTA burner was able to produce NO(sub x) emissions 20% lower than the low-NO(sub x) burner, 76 ppmv vs. 94 ppmv, at a burner stoichiometric ratio (BSR) of 0.7 and a normalized stoichiometric ratio (NSR) of 2.0. CFD modeling was used to investigate the application of RRI for NO(sub x) control on a 180 MW(sub e) wall-fired, PC boiler. A NO(sub x) reduction of 37% from baseline (normal operation) was predicted using ALTA burners with RRI to produce a NO(sub x) emission rate of 0.185 lb/MBtu at the horizontal nose of the boiler. When combined with SNCR, a NO(sub x) emission rate of 0.12-0.14 lb/MBtu can be expected when implementing a full ALTA system on this unit. Cost effectiveness of the full ALTA system was estimated at $2,152/ton NO(sub x) removed; this was less than 75% of the cost estimated for an SCR system on a unit of this size.