Dimensional Analysis of Continuous High-Capacity Electrodispersion of Aqueous Based Liquids in an Organic Continuous Phase.

摘要

High-intensity electric fields can be used to disperse aqueous-based solutions in a relatively nonconducting immiscible organic phase. Dimensional analysis of electrical dispersion performance from a single grounded nozzle between two charged electrodes can be characterized in terms of five dimensionless groups: an electrode height; nozzle-electrode distance; a nozzle Reynolds number; an electrical Bond number, which relates electrical to surface forces; and a Taylor number, which relates electrical to viscous forces. Experimental results on the electrodispersion of water in 2-ethyl-1-hexanol indicate that pulsed dc fields can accomplish electrodispersion utilizing a lower rms/voltage than steady dc fields. In addition, the pulsed-field behavior varies with pulse frequency with 200 Hz fields being more effective for higher continuous-phase viscosities while 2000 Hz fields are more effective when the viscosity is lower. A steady dc field displays invariant behavior with changing viscosity. In the case of the 2000 Hz field, the Taylor number remains constant for all cases tested thus indicating that the dispersion behavior is controlled by the dynamic interactions of the forces induced by the transient field with the stability of the liquid stream emanating from the nozzle. 18 refs., 8 figs.