Modification of surface mechanical properties of high-chromium tool steel by carbon-implanted codeposited Fe-Ti films.

摘要

An iron-titanium film 300 nm thick was deposited on a tool steel (1.55% C, 0.3% Si, 0.3% Mn, 12% Cr, 0.8% Mo, and 0.8% V) by coevaporation of Fe and Ti. Subsequently this surface film was implanted with carbon at energies of 55, 120, and 200 keV to a total fluence of 1.24 (times) 10(sup 18) C(sup +)/cm(sup 2). This treatment produced a surface hardness of 15 GPa. The effect of this coating on unlubricated wear and friction was tested in air at a relative humidity of 10% in a pin-on-disc tester using a 440C pin as a counterface. The sliding mechanism of the untreated substrate was found to be based on the transfer of pin material and subsequent growth of uneven oxide hillocks on the wear track. Oxide scales were observed also on a wear scar of the pin, presumably as a result of back-deposition. In contrast, the sliding mechanism on the coated sample was drastically different. A more uniform transfer film originating in the coating was found on the pin, resulting in sliding between identical materials. No wearthrough of the coating occurred during the test of 5000 cycles at a Hertzian pressure of 835 MPa, and the surface of the wear track showed extreme smoothness to the very end of the test. The friction coefficient was decreased from 0.7 for the uncoated to 0.2 for the coated surface. The wear track on the coated surface was also found to be slightly oxidized, as determined by a nuclear reaction ((sup 16)O(d,p)(sup 17)O). The reduction of friction was mainly attributed to the increased hardness of the counterfaces and an adequate but controlled oxidation. 15 refs., 7 figs., 2 tabs.