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Hydrolysis of 2,4-Dinitrophenyl Phosphate in Hydrophobic Ammonium Salts

机译：疏水铵盐中2,4-二硝基苯基磷酸酯的水解

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摘要

Reaction rates of spontaneous dephosphorylation of the dianion of 2,4-dinitrophenyl phosphate (2,4-DNPP) in solutions of hydrophobic ammonium ions are examined and compared to those in cationic micelles.

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作者
Bunton, C. A.; Quan, C.;
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年度 1985
页码 p.1-4
总页数 4
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Reaction kinetics; Hydrolysis; Phosphates; Phenyl radicals; Ammonium compounds; Cations; Colloids; Hydrophobic properties; Ions; Salts; Reprints;

机译：反应动力学;水解;磷酸盐;苯基;铵化合物;阳离子;胶体;疏水性;离子;盐;重印;

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专利

1. A promiscuous dicopper(II) system promoting the hydrolysis of bis(2,4-dinitrophenyl)phosphate: Gaining mechanistic insight by means of structural and spectroscopic DFT studies [J] . Rey N.A., Neves A., De Almeida W.B., International Journal of Quantum Chemistry . 2010,第7期

机译：混杂双铜（II）系统促进双（2,4-二硝基苯基）磷酸酯的水解：通过结构和光谱DFT研究获得机理的见解
2. A promiscuous dicopper(II) system promoting the hydrolysis of bis(2,4-dinitrophenyl)phosphate: Gaining mechanistic insight by means of structural and spectroscopic DFT studies [J] . Rey N.A., Neves A., De Almeida W.B., International Journal of Quantum Chemistry . 2010,第7期

机译：混杂双铜（II）系统促进双（2,4-二硝基苯基）磷酸酯的水解：通过结构和光谱DFT研究获得机理的见解
3. Catalytic effect of a dinuclear [Fe-2(III)(OH)(OH2)1 complex in the hydrolysis of bis(2,4-dinitrophenyl) phosphate [J] . Longhinotti E, Domingos JB, Szpoganicz B, Inorganica Chimica Acta . 2005,第6期

机译：双核[Fe-2（III）（OH）（OH2）1络合物在双（2,4-二硝基苯基）磷酸酯水解中的催化作用
4. Chemical recycling of PET by alkaline hydrolysis in the presence of quaternary phosphonium and ammonium salts as phase transfer catalysts [C] . R. Lopez-Fonseca, M. P. Gonzalez-Marcos, J. R. Gonzalez-Velasco International Conference on Waste Management and Environment . 2008

机译：在季鏻和铵盐作为相转移催化剂存在下碱性水解的化学回收
5. Developing artificial proteases and nucleases: Catalytic hydrolysis of unactivated amides, nitriles and phosphates. Part~I. Hydrolysis of phosphate esters promoted by cobalt(III) complexes. Part~II. Hydration of nitriles catalyzed by cobalt(III) complexes. Part~III. Hydrolysis of amides promoted by cobalt(III) complexes. [D] . Kim, Jung Hee. 1992

机译：开发人造蛋白酶和核酸酶：催化水解未活化的酰胺，腈和磷酸盐。第一部分钴（III）配合物促进的磷酸酯的水解。第二部分钴（III）配合物催化的腈水合。第三部分钴（III）配合物促进的酰胺水解。
6. Catalytic Hydrolysis of Phosphate Monoester by Supramolecular Complexes Formed by the Self-Assembly of a Hydrophobic Bis(Zn2+-cyclen) Complex, Copper, and Barbital Units That Are Functionalized with Amino Acids in a Two-Phase Solvent System [O] . Yuya Miyazawa, Akib Bin Rahman, Yutaka Saga, 2015

机译：疏水性双（Zn2 + -cycln）配合物，铜和巴比妥单元的自组装形成的超分子配合物，在两相溶剂系统中催化水解磷酸单酯
7. Catalyses by Polymer Complexes. V. The Heterotropic (Allosteric) Interaction of Histamine- and Hydroxamate-Containing Polymer Catalysts with Hydrophobic Ammonium Salts in the Hydrolysis of Phenyl Esters [O] . Seiji Shinkai, Kunio Tou, Toyoki Kunitake 1977

机译：聚合物配合物催化。 V.含有组胺和含羟肟酸酯的聚合物催化剂在苯酯水解中具有疏水性铵盐的异络（变构）相互作用
8. Hydrolysis of 2,4-Dinitrophenyl Phosphate in Normal and Reverse Micelles [R] . DelRosso, F., Bartoletti, A., DiProfio, P., 1995

机译：正磷酸酯和反胶束中2,4-二硝基苯基磷酸酯的水解

Hydrolysis of 2,4-Dinitrophenyl Phosphate in Hydrophobic Ammonium Salts

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