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Henry's law constant for hydrogen in natural water and deuterium in heavy water

机译:天然水中氢和重水中氘的亨利定律常数

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The results of measurements of the Henry's law constant near infinite dilution are reported for solutions of H-2 in H2O and D-2 in D2O at high temperatures (170 similar to 300 degreesC). The experimental procedure involved the use of a palladium/hydrogen (or deuterium) electrical resistance sensor. Values of K-H(infinity) for H-2-H2O solutions agree closely with published data. Values of K-H(infinity) for D-2-D2O solutions are lower than those for H-2-H2O solutions. With increasing concentrations of H-2 in H2O and D-2 in D2O the Henry's law coefficients decrease. This is attributed to non-ideality in the gas phase. [References: 10]
机译:报告了在高温(170类似于300摄氏度)下H-2O中的H-2和D2O中的D-2溶液的接近无限稀释的亨利定律常数的测量结果。实验过程涉及使用钯/氢(或氘)电阻传感器。 H-2-H2O解决方案的K-H(无穷大)值与已公开的数据非常吻合。 D-2-D2O溶液的K-H(无穷大)值低于H-2-H2O溶液的K-H(无穷大)值。随着H2O中H-2浓度和D2O中D-2浓度的增加,亨利定律系数减小。这归因于气相的不理想。 [参考:10]

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