首页> 外文期刊>Synthesis: International Journal of Methods in Synthetic Organic Chemistry >Total synthesis of aculeatins A, B and D and 6-epi-aculeatin D via an asymmetric aldol approach 1
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Total synthesis of aculeatins A, B and D and 6-epi-aculeatin D via an asymmetric aldol approach 1

机译:通过不对称的羟醛方法完全合成aculeatins A,B和D和6-epi-aculeatin D 1

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摘要

Simple and efficient stereoselective total syntheses of aculeatins A, B and D and 6-epi-aculeatin D starting from 1-tetradecanal have been accomplished. The synthesis is based on the Crimmins aldol reaction involving a chiral auxiliary.
机译:从1-四癸醛开始的aculeatins A,B和D和6-epi-aculeatin D的简单,有效的立体选择性总合成已经完成。该合成基于涉及手性助剂的Crimmins aldol反应。

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