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Influence of different reduction agents for pyrometallurgical treatment of EAF dust

机译:不同还原剂对电炉粉尘火法冶金处理的影响

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摘要

During steel production either with EAF or BOF, 15 to 20 kg of dust/t of steel produced are formed, brought out by the gas stream and collected in the filter system. 20 years ago hardly any one knew about the problems related to these residues, but nowadays because of high zinc and lead contents in conjunction with the classification as hazardous waste they generate an additional expense factor. From the metallurgical view the high zinc containing dusts from the steel industry seem to be an interesting secondary raw material for the zinc industry. But because of different unwanted elements it is difficult to manage an economic recycling. As long as the land filing of these residues is still a competitive way of treatment, the different recycling options have to be critically investigated. The remaining room for improvement has to be utilized and research into possible alternative recycling routes has to be done. Referring to the pyrometallurgical treatment routes the influence of different reducing agents on the quality of products and residues form the base for further investigations. This paper describes the results of thermal treatment of an EAF dust in a vertical retort with the use of different reducing agents. Especially the character of the residue formed, that should be reused in the steel mill, is discussed. Beyond this, advantages and disadvantages of carbon and hydrogen as reduction agents are shown and the possibility of a combined use was judged.
机译:在用电弧炉或转炉生产钢的过程中,每吨钢产生15至20公斤的粉尘,被气流带走并收集在过滤系统中。 20年前,几乎没人知道与这些残留物有关的问题,但是如今,由于锌和铅的含量很高,再加上分类为危险废物,它们产生了额外的费用因素。从冶金学的角度来看,钢铁行业的高含锌粉尘似乎是锌行业有趣的辅助原料。但是由于不同的有害元素,很难管理经济的回收利用。只要这些残留物的土地备案仍然是一种竞争性的处理方式,就必须认真研究不同的回收选择。必须利用剩余的改进空间,并且必须对可能的替代回收途径进行研究。参考火法冶金处理路线,不同还原剂对产品质量的影响,残留物构成进一步研究的基础。本文介绍了使用不同的还原剂对立式干馏炉中的电弧炉粉尘进行热处理的结果。尤其讨论了形成的残留物的特征,应在钢厂中重复使用。除此之外,还显示了碳和氢作为还原剂的优缺点,并判断了组合使用的可能性。

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