HIGHLY ERYTHRO-SELECTIVE 2-CYCLOHEXENYLATION OF ALDEHYDES PROMOTED BY ACTIVE METAL BISMUTH FROM NABH4 AND BICL3

摘要

In the presence of Bu4NBr in DMF solution, the reaction of 3-bromocyclohexene and active metal bismuth from NaBH4 and BiCl3 with aromatic and aliphatic aldehydes provides excellent erythro-selective products. [References: 10]