Syntheses, crystal, molecular structures, and solution studies of Cu(II), Co(II), and Zn(II) coordination compounds containing pyridine-2,6-dicarboxylic acid and 1,4-pyrazine-2,3-dicarboxylic acid: Comparative computational studies of Cu(II) and Zn(II) complexes

摘要

Three new coordination compounds of Cu(II), Co(II), and Zn(II) based on different dicarboxylicacids formulated as (AcrH)[Cu(pydc)(pydcH)]?5H2O (1)(2a-4mpyH)2[M(pyzdc) _2(H _2O) _2] 6H _2O; M = Co(II) (2) and Zn(II) (3) have been synthesized and structurally characterized by elemental analyses, IR spectroscopy, and single crystal X-ray diffraction (where pydcH2 = pyridine- 2,6-dicarboxylic acid; Acr = acridine; 2a-4mpy = 2- amino-4-methyl pyridine; pyzdcH _2 = 1,4-pyrazin-2, 3-dicarboxylic acid). In all cases, the metal centers have distorted octahedral coordination geometries. Through hydrogen bonding (such as O-H?O and N-H?O) and/or slipped or offset φ- φ stacking interactions, 3D supramolecular networks are constructed in these complexes. In the crystalline network, O-H?O hydrogen bonding create (H _2O)n water clusters, so the hydrogen bond interactions play an important role in sustaining of the supramolecular solid-state architectures in compounds 1-3. The species in the solution media were studied by potentiometric method. The protonation constants of 2a-4mpy, 2-apy = 2-aminopyridine, pydc and pyzdc in aqueous solution, pydc and Acr in a 50% dioxane-50% water (v/v) solvent, as well as the equilibrium constants for three proton-transfer systems, pyzdc-2a-4mpy, pydc-2-apy, and pydc-Acr were calculated using potentiometrical method. The stoichiometry and stability of complexation during the first proton-transfer system with Cu ~(2+), Co ~(2+), and Zn ~(2+) ions and also the second proton-transfer system with Fe ~(3+) and Cr ~(2+) ions in aqueous solution were investigated by potentiometric pH titration method, from point of comparison view of their behaviors in the solution state. The stoichiometry and stability of complexation of third system with Cu ~(2+) and Zn ~(2+), metal ions in 50% dioxane-50% water (v/v) solvent were also investigated by the cited method. The stoichiometry of the most complex species in solution were compared with corresponding crystalline metal ion complexes. Furthermore, DFT calculations have been carried out on the Cu(II) and Zn(II) complexes in the presence of pydcH2 and pyzdcH _2 in order to better understanding of their molecular orbital structures of HOMO and LUMO.