High resolution applications of laser-induced breakdown spectroscopy for environmental and forensic applications

摘要

Laser-induced breakdown spectroscopy (LIBS) has been used in the elemental analysis for a variety of environmental samples and as a proof of concept for a host of forensic applications.In the first application,LIBS was used for the rapid detection of carbon from a number of different soil types.In this application,a major breakthrough was achieved by using a multivariate analytical approach that has brought us closer towards a "universal calibration curve".In a second application,it has been demonstrated that LIBS in combination with multivariate analysis can be employed to analyze the chemical composition of annual tree growth rings and correlate them to external parameters such as changes in climate,forest fires,and disturbances involving human activity.The objectives of using this technology in fire scar determinations are:1) To determine the characteristic spectra of wood exposed to forest fires and 2) To examine the viability of this technique for detecting fire occurrences in stems that did not develop fire scars.These examples demonstrate that LIBS-based techniques are inherently well suited for diverse environmental applications.LIBS was also applied to a variety of proof of concept forensic applications such as the analysis of cremains (human cremation remains) and elemental composition analysis of prosthetic implants.