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首页> 外文期刊>Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy >New method to determine the optical rotatory dispersion of inorganic crystals applied to some samples of Carpathian Quartz
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New method to determine the optical rotatory dispersion of inorganic crystals applied to some samples of Carpathian Quartz

机译:确定应用于喀尔巴阡石英样品的无机晶体旋光色散的新方法

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A new method to determine the optical rotatory dispersion (ORD) in the visible range, based on a channeled spectrum obtained with a uniax inorganic crystal introduced between two crossed polarizers with its optical axis parallel to the light propagation direction is detailed in this paper. When the studied inorganic crystals are transparent, this method permits the estimation of the optical rotatory dispersion in the visible range, for which the cheap polarizers are available. The speed of the measurements is very high, because the estimations are made from the channeled spectrum obtained for a single arrangement of the optical components. By using a computer, ORD is quickly determined for the visible range. The results obtained by this method for some Carpathian Quartz samples are consistent with those from literature. The proposed method can be also applied in UV and IR spectral ranges, when the anisotropic layers are transparent and the linearly polarized radiations can be obtained. (C) 2014 Elsevier B.V. All rights reserved.
机译:本文详细介绍了一种基于可见光谱的新方法,该光谱基于在两个交叉偏振器之间引入的单轴无机晶体的光轴与光传播方向平行的单轴无机晶体而获得的通道光谱。当所研究的无机晶体是透明的时,这种方法可以估算可见光范围内的旋光色散,为此可以使用便宜的偏振器。测量的速度非常快,因为估算是根据为光学组件的单个布置获得的通道光谱进行的。通过使用计算机,可以快速确定可见范围的ORD。通过这种方法获得的一些喀尔巴阡石英样品的结果与文献中的结果一致。当各向异性层是透明的并且可以获得线性偏振辐射时,所提出的方法也可以应用于UV和IR光谱范围。 (C)2014 Elsevier B.V.保留所有权利。

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