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Silica Crown Refractory Corrosion in Glass Melting Furnaces

机译:玻璃熔炉中的二氧化硅冠状耐火材料腐蚀

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摘要

The critical parameters of silica refractories, such as compressive strength, bulk, density, quantity of silica, microstructure and porosity were evaluated of unused and used bricks to line the crowns of glass furnaces, when the rate of corrosion of crowns were about 2 times greater. The change of these parameters, the chemical composition and formation of the microcracks in the used silica refractories material vsere studied. It was established that the short time at service of container glass furnace crown can be related to low quality of silica brick: high quantity oj'CaO and impurities, low quantity of silica, low quantity of silica, transferred to tridymite and cristobalite and formation of 5 -10 ìm and more than 100 ìm cracks in the crown material. The main reason of corrosion high quality silica bricks used to line the crown of electrovacuum glass furnace is the multiple cyclic change of crown temperature at 1405 - 1430 °C range in the initial zone of crown and at 1575 - 1605 °C range in the zone of highest temperatures.
机译:当顶冠的腐蚀速率约为2倍时,评估了未使用和用过的砖砌成的玻璃炉顶的硅质耐火材料的关键参数,例如抗压强度,体积,密度,硅石数量,微结构和孔隙率。 。研究了用过的二氧化硅耐火材料中这些参数的变化,化学成分和微裂纹的形成。可以确定的是,容器玻璃炉顶使用时间短可能与二氧化硅砖的质量低有关:大量的氧化钙和杂质,二氧化硅的数量少,二氧化硅的数量少,转移到鳞石英和方石英中以及形成了硅藻土。在表冠材料中出现5 -10ìm和100ìm以上的裂纹。腐蚀用于电真空玻璃窑炉炉顶的优质硅砖的主要原因是,在炉顶初始区域中,炉顶温度在1405-1430°C范围内,在区域1575-1605°C,炉顶温度呈多周期变化最高温度。

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