Effects of Electronic Correlations for Adiabatic Electrochemical Reactions of Electron Transfer in Electrode Models with Nearly Empty and Nearly Filled Conduction Bands: Diagram of Kinetic Modes

摘要

A diagram of kinetic modes (DKM), whose parts correspond to different electron transfer types, for any electrode's Fermi energy ε_F and any finite value of its conduction band's width B is studied. Important differences between DKM for any ε_F and B and DKM in a model of a surface molecule for an electrode-reactant system are pointed out. DKM for electrode models with nearly empty and nearly filled conduction bands proposed earlier are discussed. Expressions for outermost curves of DKM are derived for some special cases within these models.