Synthesis of nano-sized Yb_3Al_5O_12 powders by the urea co-precipitation method

摘要

Nano-sized polycrystalline ytterbium aluminum garnet (YbAG, Yb_3Al_5O_12) powders were successfully synthesized by a simple urea coprecipitation method. The thermal behavior of the YbAG precursor was investigated. The calcined amorphous YbAG precursor was directly converted to 20-30 nm monophase YbAG at as low as temperature 900 deg, without any other intermediate phases. The nano-sized YbAG powders calcined at 900 deg distributed evenly with a slight aggregation, and the specific surface area of the powders reached 29.7 m~2g~-1. The absorption spectrum of the YbAG powders was measured, and there were two strong absorption peaks centered at 931 and 965 nm. The results did not correspond to the absorption peaks of Yb:YAG crystal exactly, as the lattice parameters were different between YbAG and YAG.