An Efficient One-Pot Asymmetric Synthesis of Biaryl Compounds via Diels-Alder/Retro-Diels-Alder Cascade Reactions

Yongxiang Liu; Kui Lu; Mingji Dai; Kai Wang; Wanqing Wu; Jiahua Chen; Junmin Quan; Zhen Yang

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An Efficient One-Pot Asymmetric Synthesis of Biaryl Compounds via Diels-Alder/Retro-Diels-Alder Cascade Reactions

机译：通过Diels-Alder / Retro-Diels-Alder级联反应有效地一锅不对称地合成联芳基化合物

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A single-step chirality transfer method for the synthesis of axially chiral biaryl compounds by construction of the second aromatic ring via a Diels-Alder/retro-Diels-Alder cascade reaction is reported. This methodology should find broad application in the synthesis of natural products and asymmetric catalysts.

机译：报道了一种通过Diels-Alder / retro-Diels-Alder级联反应通过构建第二个芳环来合成轴向手性联芳基化合物的一步式手性转移方法。该方法应在天然产物和不对称催化剂的合成中得到广泛应用。

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《Organic letters》 |2007年第5期|共4页
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Yongxiang Liu; Kui Lu; Mingji Dai; Kai Wang; Wanqing Wu; Jiahua Chen; Junmin Quan; Zhen Yang;
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正文语种 eng
中图分类有机化学;
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1. An Efficient One-Pot Asymmetric Synthesis of Biaryl Compounds via Diels-Alder/Retro-Diels-Alder Cascade Reactions [J] . Yongxiang Liu, Kui Lu, Mingji Dai, Organic letters . 2007,第5期

机译：通过Diels-Alder / Retro-Diels-Alder级联反应有效地一锅不对称地合成联芳基化合物
2. Efficient one-pot synthesis of biologically interesting diverse furo[2,3-b]pyran-6-ones by rhodium(II)-catalyzed cascade reactions of diazo compound with ethynyl compounds [J] . Somai Magar K.B., Lee Y.R., Kim S.H. Tetrahedron . 2013,第44期

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4. ONE-POT REGIOSPECIFIC SYNTHESIS OF NEW SUBSTITUTED 1,4-BENZOXAZINES THROUGH AN INVERSE ELECTRON-DEMAND HETERO DIELS-ALDER REACTION OF SIMULTANEOUSLY ELECTROGENERATED DIENE AND DIENOPHILE. [C] . MARTINE LARGERON, MARC VUILHORGNE, ESTELLE BLATTES The Meeting of the Electrochemical Society . 2001

机译：通过同时发电二烯和腙反应的逆电子杂差二胶剂反应，单壶细胞再性合成新型取代的1,4-苯并恶嗪。
5. Part I. One-pot synthesis of secondary alcohols and one-pot asymmetric synthesis of secondary propargylic alcohols. Part II. Redox isomerization of secondary propargylic alcohols to enones. Part III. Synthesis study towards C9-C14 fragment of (+)-discodermolide. Part IV. Asymmetric synthesis of anti, anti-stereotriad building blocks for polypropionate natural products [D] . Xie, Qiuzhe 2007

机译：第一部分：仲醇的一锅法合成和仲炔丙醇的一锅法不对称合成。第二部分仲炔丙醇的氧化还原异构化为烯酮。第三部分（+）-discodermolide C9-C14片段的合成研究。第四部分聚丙烯酸酯天然产物的抗，抗立体三环构建基的不对称合成
6. Pd-catalyzed asymmetric Suzuki–Miyaura coupling reactions for the synthesis of chiral biaryl compounds with a large steric substituent at the 2-position [O] . Yongsu Li, Bendu Pan, Xuefeng He, 2020

机译：PD-催化的不对称铃木Miyaura偶联反应在2-位合成手性辅导芳烃化合物
7. An Efficient One-Pot Asymmetric Synthesis of Biaryl Compounds via Diels-Alder/Retro-Diels-Alder Cascade Reactions [O] . -1

机译：通过Diels-Alder / Retro-Diels-Alder Cascade反应的高效单罐不对称合成芳基化合物

An Efficient One-Pot Asymmetric Synthesis of Biaryl Compounds via Diels-Alder/Retro-Diels-Alder Cascade Reactions

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