Palladium-Catalyzed Oxidation of Soc-Protected N-Methylamines with lOAc as the Oxidant:A Hoc-Directed sp~3 C-H Bond Activation

Dong-Hui Wang; Xue-Shi Hao; Di-Fu Wu

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Palladium-Catalyzed Oxidation of Soc-Protected N-Methylamines with lOAc as the Oxidant:A Hoc-Directed sp~3 C-H Bond Activation

机译：以lOAc为氧化剂的钯催化的Soc保护的N-甲胺的氧化：Hoc定向的sp〜3 C-H键活化

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摘要

Pd-catalyzed selective oxidation of Boc-protected N-methylamines with lOAc as the oxidant is described.Evidence for the involvement of a Boc-directed C-H activation process is provided.

机译：描述了以LOAc为氧化剂的Pd催化的Boc保护的N-甲胺的选择性氧化。提供了Boc定向C-H活化过程参与的证据。

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《Organic letters》 |2006年第15期|共4页
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Dong-Hui Wang; Xue-Shi Hao; Di-Fu Wu;
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正文语种 eng
中图分类有机化学;
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1. Palladium-Catalyzed Oxidation of Soc-Protected N-Methylamines with lOAc as the Oxidant:A Hoc-Directed sp~3 C-H Bond Activation [J] . Dong-Hui Wang, Xue-Shi Hao, Di-Fu Wu Organic letters . 2006,第15期

机译：以lOAc为氧化剂的钯催化的Soc保护的N-甲胺的氧化：Hoc定向的sp〜3 C-H键活化
2. Palladium-catalyzed oxidation of Boc-protected N-methylamines with IOAc as the oxidant: A Boc-directed sp(3) C-H bond activation [J] . Wang DH, Hao XS, Wu DF, Organic letters . 2006,第15期

机译：以IOAc为氧化剂的Boc保护的N-甲胺的钯催化氧化：Boc定向的sp（3）C-H键活化
3. Palladium-catalyzed oxidation of Boc-protected N-methylamines with IOAc as the oxidant: A Boc-directed sp(3) C-H bond activation [J] . Wang DH, Hao XS, Wu DF, Organic letters . 2006,第15期

机译：以IOAc为氧化剂的Boc保护的N-甲胺的钯催化氧化：Boc定向的sp（3）C-H键活化
4. Reactivity and Selectivity Descriptors for the Activation of C-H Bonds in Hydrocarbons and Oxygenates on Metal Oxides [C] . Prashant Deshlahra, Enrique Iglesia AIChE Annual Meeting . 2016

机译：反应性和选择性描述符用于在金属氧化物中活化C-H键和含氧化合物
5. Palladium-mediated carbon-carbon bond formation: Methodology and mechanism. Part I: Palladium-catalyzed alpha-arylation of aryl nitromethanes, phosphonoacetates, and phosphine oxides. Part II: Mechanistic study of the palladium-mediated chemoselective activation of C(sp3)-H bonds. [D] . VanGelder, Kelsey Faith. 2016

机译：钯介导的碳-碳键形成：方法和机理。第一部分：芳族硝基甲烷，膦酰基乙酸酯和氧化膦的钯催化α-芳基化反应。第二部分：钯介导的C（sp3）-H键的化学选择性激活的机理研究。
6. Scope and Limitations of Auxiliary-Assisted Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 C-H Bonds [O] . Enrico T. Nadres, Gerson Ivan Franco Santos, Dmitry Shabashov, -1

机译：sp2和sp3 C-H键的辅助钯催化的芳基化和烷基化的范围和限制
7. Palladium-Catalyzed Oxidation of Boc-Protected N-Methylamines with IOAc as the Oxidant: A Boc-Directed sp3 C-H Bond Activation [O] . -1

机译：用IOAC作为氧化剂的钯催化的Boc保护的N-甲胺的氧化：Boc染色的SP3 C-H键活化

Palladium-Catalyzed Oxidation of Soc-Protected N-Methylamines with lOAc as the Oxidant:A Hoc-Directed sp~3 C-H Bond Activation

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