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Effect of interfacial-active elements addition on the incorporation of micron-sized SiC particles in molten pure aluminum

机译:界面活性元素的添加对熔融铝中微米级SiC颗粒掺入的影响

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摘要

Ceramic particles generally have poor wettability by liquid metal, leading to a major drawback in fabrication of cast metal matrix composites (MMCs). In this work, the effect of 1 wt. % of Ca, Mg, Si, Ti, Zn and Zr interfacial-active alloying elements was studied on the incorporation of micron-sized SiC particles into the molten pure aluminum using the vortex casting method at 680 °C. The results indicated that Ti, Zr, Zn and Si were not positively effective in improving particulate incorporation, while Ca and especially Mg were very efficient at increasing the incorporation of ceramic particles into the molten Al. Also, it was revealed that Al_3Ti, and Al_3Zr intermetallic phases were formed for samples containing Ti and Zr, making hybrid MMCs with a higher amount of hardness. Finally, it was found that a reaction layer between Al and SiC particles was formed at the Al/SiC interface for all of the samples, expect for the ones containing Si and Ti, indicating that for most of the samples at 680 °C an exothermic reaction took place between the Al and SiC particles.
机译:陶瓷颗粒通常对液态金属的润湿性很差,从而导致在铸造金属基复合材料(MMC)的制造中存在主要缺陷。在这项工作中,1 wt。通过在680°C的涡流铸造方法中,将微米级SiC颗粒掺入熔融纯铝中,研究了%Ca,Mg,Si,Ti,Zn和Zr界面活性合金元素。结果表明,Ti,Zr,Zn和Si在改善颗粒结合方面不是积极有效的,而Ca尤其是Mg在增加陶瓷颗粒在熔融Al中的结合方面非常有效。另外,还揭示了对于包含Ti和Zr的样品形成了Al_3Ti和Al_3Zr金属间相,从而使得混合MMC具有更高的硬度。最后,发现在所有样品的Al / SiC界面上都形成了Al和SiC颗粒之间的反应层,对于包含Si和Ti的样品来说,这是期望的,这表明对于大多数样品,在680°C时放热Al和SiC颗粒之间发生反应。

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