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Validation of Elongational Stress to Trigger Melt Fracture

机译:触发熔体破裂的拉伸应力的验证

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In 1926 Ostwald found for structural viscous fluids' a critical flow rate at the transition from the laminar to a new type of irregular flow, far below the rate for Reynold's established eddy turbulence. Tordella localized his LDPE melt flow instabilities in 1956, observing the partition of soft markers at the constrict of a glass pipe and tracing it to a crucial value of the shear rate in a corresponding capillary die. He also introduced the label 'melt fracture' after hearing a related crackling noise. Jet the expression 'flow instability' is to be recommended. In 1960 Reiner predicted, that the polymer fluid must loose structural coherence after the strain rate becomes larger than the rate of relaxation. In 1972 Hurlimann found, that a LDPE melt strand at the inlet of a die is stretched at a nearly constant elongational force, and that the flow transition occurs at a critical value of elongational stress. This dynamic property is much less dependent on temperature and other physical parameters than formerly used kinematic criteria. In extensive investigations, Cogswell also drew attention to the correlation of die inlet pressure loss, elongational stress and strain rate at the transition to flow instability. For now sixty years many more researchers ventured to find the key to these phenomena, but even an extensive compilation of 2011 spotted no conclusive interpretation. Let us return to the basic physics.
机译:1926年,奥斯特瓦尔德发现结构性粘性流体在从层流向新型不规则流动过渡时的临界流速,远低于雷诺既定涡流的流速。 Tordella在1956年确定了其LDPE熔体流动的不稳定性,观察到玻璃管狭窄处的软标记分布,并在相应的毛细管模具中将其标记为剪切速率的关键值。在听到相关的crack啪声之后,他还推出了标签“熔体破裂”。推荐使用“流量不稳定性”一词。 Reiner在1960年预测,在应变率变得大于松弛率之后,聚合物流体必须失去结构一致性。 1972年Hurlimann发现,模头入口处的LDPE熔体线材以几乎恒定的伸长力拉伸,而流动转变发生在伸长应力的临界值处。与以前使用的运动学标准相比,这种动态特性对温度和其他物理参数的依赖性小得多。在广泛的研究中,Cogswell还提请注意模具入口压力损失,流变不稳定过渡过程中的拉伸应力和应变率之间的关系。六十年来,更多的研究人员冒险寻找这些现象的关键,但即使是2011年的大量汇编也没有发现结论性的解释。让我们回到基础物理学。

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